Band structure changes of single-wall carbon nanotubes by the presence of an ionic shell

被引:9
作者
Dobrokhotov, VV [1 ]
Berven, CA [1 ]
机构
[1] Univ Idaho, Dept Phys, Moscow, ID 83844 USA
基金
美国国家科学基金会;
关键词
band structure; carbon nanotubes; chemical sensors;
D O I
10.1016/j.physe.2005.11.001
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report the change of the band structure of two types of carbon nanotubes due to the presence of all isolated, non-conducting, uniformly charged shell held at a fixed distance above their surfaces. We find that, depending on the chirality of the nanotube, the strain on the lattice causes the dispersion relationships to change. This change can result in a modification of the band structure which can induce a metal-semiconductor transition. We consider these effects as a mechanism for heavy-metal ion sensing by functionalized carbon nanotubes. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:160 / 164
页数:5
相关论文
共 29 条
[1]   Electromechanical properties of metallic, quasimetallic, and semiconducting carbon nanotubes under stretching [J].
Cao, J ;
Wang, Q ;
Dai, HJ .
PHYSICAL REVIEW LETTERS, 2003, 90 (15) :4
[2]   Hydrostatic pressure effects on the structural and electronic properties of carbon nanotubes [J].
Capaz, RB ;
Spataru, CD ;
Tangney, P ;
Cohen, ML ;
Louie, SG .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2004, 241 (14) :3352-3359
[3]   Glucose biosensor based on multi-walled carbon nanotube modified glassy carbon electrode [J].
Dai, YQ ;
Shiu, KK .
ELECTROANALYSIS, 2004, 16 (20) :1697-1703
[4]   METAL-COORDINATION INTERACTIONS IN THE TEMPLATE-MEDIATED SYNTHESIS OF SUBSTRATE-SELECTIVE POLYMERS - RECOGNITION OF BIS(IMIDAZOLE) SUBSTRATES BY COPPER(II) IMINODIACETATE CONTAINING POLYMERS [J].
DHAL, PK ;
ARNOLD, FH .
MACROMOLECULES, 1992, 25 (25) :7051-7059
[5]   PHYSICS OF CARBON NANOTUBES [J].
DRESSELHAUS, MS ;
DRESSELHAUS, G ;
SAITO, R .
CARBON, 1995, 33 (07) :883-891
[6]  
DURGUN E, 2001, PHYS REV B, V67
[7]   SYNTHESIS AND EVALUATION OF NEW POLYURETHANE-BASED MATERIAL FOR ION SEPARATION [J].
FAVREREGUILLON, A ;
DUMONT, N ;
DUNJIC, B ;
LEMAIRE, M .
TETRAHEDRON LETTERS, 1995, 36 (36) :6439-6442
[8]   Radial electromechanical properties of carbon nanotubes [J].
Gómez-Navarro, C ;
de Pablo, PJ ;
Gómez-Herrero, J .
ADVANCED MATERIALS, 2004, 16 (06) :549-+
[9]   Synthesis of castasterone selective polymers prepared by molecular imprinting [J].
Kugimiya, A ;
Matsui, J ;
Abe, H ;
Aburatani, M ;
Takeuchi, T .
ANALYTICA CHIMICA ACTA, 1998, 365 (1-3) :75-79
[10]   On the effective elastic moduli of carbon nanotubes for nanocomposite structures [J].
Lau, KT ;
Chipara, M ;
Ling, HY ;
Hui, D .
COMPOSITES PART B-ENGINEERING, 2004, 35 (02) :95-101