Crystal structure of [Me3Sb-SbMe2]2[(MeSbBr3)2], a trimethylstibine adduct of the dimethylstibenium ion or a stibinostibonium salt?

被引：34

作者：

Althaus, H ^{[1
]}

Breunig, HJ ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, D-28334 Bremen, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a905837k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Scrambling reactions of dimethylantimony bromide in absence of solvent give the ionic complex [Me3Sb-SbMe2](2)-[(MeSbBr3)(2)], with cations consisting of pyramidal Me3Sb bound to bent Me2Sb units through short (282 pm) Sb-Sb bonds and dimeric anions adopting the geometry of edge sharing tetragonal pyramids where methyl groups are in apical trans positions.

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页码：1971 / 1972

页数：2

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