Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds

被引:267
作者
Kita, Yasuyuki [1 ]
Morimoto, Koji [1 ]
Ito, Motoki [1 ]
Ogawa, Chieko [1 ]
Goto, Akihiro [1 ]
Dohi, Toshifumi [1 ]
机构
[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan
关键词
C-H ACTIVATIONS; BOND FORMATION; DERIVATIVES; ARENES; POLYTHIOPHENES; THIOPHENE; BIARYLS;
D O I
10.1021/ja808940n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new strategy for mixed biaryl synthesis has been developed using the hypervalent iodine(III) reagents. The unique reactivities of the sigma-heteroaryl iodine(III) intermediates generated in situ are the key element for the unusual metal catalyst-free transformations and strict control of the product selectivities.
引用
收藏
页码:1668 / +
页数:3
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