Synthesis of phosphido-bridged dinuclear complexes through sodium reduction of cis-[M{P(C6H11)(2)H}(2)Cl-2] (M=Ni or Pd)

被引：12

作者：

Giannandrea, R

Mastrorilli, P

Nobile, CF

Englert, U

机构：

[1] POLITECN, IST CHIM, I-70126 BARI, ITALY

[2] CTR CNRMISO, I-70126 BARI, ITALY

[3] RHEIN WESTFAL TH AACHEN, INST ANORGAN CHEM, D-52074 AACHEN, GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 08期

关键词：

D O I：

10.1039/a607334d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of cis-[Ni{P(C6H11)(2)H}(2)Cl-2] with sodium afforded the dinuclear nickel complex [{Ni[mu-P(C6H11)(2)][P(C6H11)(2)H]}(2)] which, in turn, reacted with CO producing [{Ni[mu-P(C6H11)(2)](CO)(2)}(2)]. The reduction of cis-[Pd{P(C6H11)(2)H]}(2)Cl-2] occurred in two steps giving first [Pd-2{mu-P(C6H11)(2)}Cl{P(C6H11)(2)H}(3)], then [{Pd[mu-P(C6H11)(2)][P(C6H11)(2)H]}(2)]. The structure of the chloride complex was determined.

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页码：1355 / 1358

页数：4

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