Electronic structure description of the μ4-sulfide bridged tetranuclear Cuz center in N2O reductase

被引：64

作者：

Chen, P

George, SD

Cabrito, I

Antholine, WE

Moura, JJG

Moura, I ^{[1
]}

Hedman, B

Hodgson, KO

Solomon, EI

机构：

[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, CQFB, Dept Quim, P-2825114 Caparica, Portugal

[2] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

[3] Med Coll Wisconsin, Biophys Res Inst, Milwaukee, WI 53226 USA

[4] Stanford Univ, Stanford Linear Accelerator Ctr, Stanford Synchrotron Radiat Lab, Stanford, CA 94309 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 05期

关键词：

D O I：

10.1021/ja0169623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spectroscopy coupled with density functional calculations has been used to define the spin state, oxidation states, spin distribution, and ground state wave function of the μ4-sulfide bridged tetranuclear CuZ cluster of nitrous oxide reductase. Initial insight into the electronic contribution to N2O reduction is developed, which involves a σ superexchange pathway through the bridging sulfide. Copyright © 2002 American Chemical Society.

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页码：744 / 745

页数：2

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