Efficient Panchromatic Organic Sensitizers with Dihydrothiazole Derivative as π-Bridge for Dye-Sensitized Solar Cells

被引：33

作者：

Chen, Cheng ^{[1
]}

Yang, Xichuan ^{[1
]}

Cheng, Ming ^{[1
]}

Zhang, Fuguo ^{[1
]}

Zhao, Jianghua ^{[1
]}

Sun, Licheng ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, DUT KTH Joint Educ & Res Ctr Mol Devices, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[2] KTH Royal Inst Technol, Sch Chem Sci & Engn, Dept Chem, Ctr Mol Devices, S-10044 Stockholm, Sweden

来源：

ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 21期

关键词：

sensitizers; dye-sensitized solar cells; D-pi-A organic dyes; panchromatic organic dyes; phenothiazine; triphenylamine; NANOCRYSTALLINE TIO2 FILMS; HIGHLY EFFICIENT; CONVERSION EFFICIENCIES; CO-SENSITIZATION; PERFORMANCE; PORPHYRIN; ACCEPTOR; PHTHALOCYANINE; MOLECULES; DESIGN;

D O I：

10.1021/am403210v

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Novel organic dyes CC201 and CC202 with dihydrothiazole derivative as pi-bridge have been synthesizedand applied in the DSSCs. With the synergy electron-withdrawing of dihydrothiazole and cyanoacrylic acid, these two novel dyes CC201 and CC202 show excellent response in the region of 500-800 nm. An efficiency as high as 6.1% was obtained for the device fabricated by sensitizer CC202 together with cobalt electrolyte under standard light illumination (AM 1.5G, 100 mW cm(-2)). These two novel D-pi-A panchromatic organic dyes gave relatively high efficiencies except common reported squaraine dyes.

引用

收藏

页码：10960 / 10965

页数：6

相关论文

共 41 条

[1] A novel blue dye for near-IR 'dye-sensitised' solar cell applications [J].

Burke, Anthony ;

Schmidt-Mende, Lukas ;

Ito, Seigo ;

Gratzel, Michael .

CHEMICAL COMMUNICATIONS, 2007, (03) :234-236

[2] Highly efficient porphyrin sensitizers for dye-sensitized solar cells [J].

Campbell, Wayne M. ;

Jolley, Kenneth W. ;

Wagner, Pawel ;

Wagner, Klaudia ;

Walsh, Penny J. ;

Gordon, Keith C. ;

Schmidt-Mende, Lukas ;

Nazeeruddin, Mohammad K. ;

Wang, Qing ;

Gratzel, Michael ;

Officer, David L. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (32) :11760-11762

[3]

Chen C., 2013, Real-time human action recognition based on depth motion maps, P1

[4] Degradation of Cyanoacrylic Acid-Based Organic Sensitizers in Dye-Sensitized Solar Cells [J].

Chen, Cheng ;

Yang, Xichuan ;

Cheng, Ming ;

Zhang, Fuguo ;

Sun, Licheng .

CHEMSUSCHEM, 2013, 6 (07) :1270-1275

[5] Effect of the acceptor on the performance of dye-sensitized solar cells [J].

Cheng, Ming ;

Yang, Xichuan ;

Chen, Cheng ;

Zhao, Jianghua ;

Tan, Qin ;

Sun, Licheng .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (40) :17452-17459

[6] Tuning the HOMO and LUMO Energy Levels of Organic Dyes with N-Carboxomethylpyridinium as Acceptor To Optimize the Efficiency of Dye-Sensitized Solar Cells [J].

Cheng, Ming ;

Yang, Xichuan ;

Zhang, Fuguo ;

Zhao, Jianghua ;

Sun, Licheng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (18) :9076-9083

[7] Dye-Sensitized Solar Cells Based on a Donor-Acceptor System with a Pyridine Cation as an Electron-Withdrawing Anchoring Group [J].

Cheng, Ming ;

Yang, Xichuan ;

Li, Jiajia ;

Chen, Cheng ;

Zhao, Jianghua ;

Wang, Yu ;

Sun, Licheng .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (50) :16196-16202

[8] Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells [J].

Choi, Hyunbong ;

Baik, Chul ;

Kang, Sang Ook ;

Ko, Jaejung ;

Kang, Moon-Sung ;

Nazeeruddin, Md. K. ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :327-330

[9] Molecular engineering of panchromatic unsymmetrical squaraines for dye-sensitized solar cell applications [J].

Choi, Hyunbong ;

Kim, Jeum-Jong ;

Song, Kihyung ;

Ko, Jaejung ;

Nazeeruddin, Md. K. ;

Graetzel, Michael .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (16) :3280-3286

[10] Synthesis of sterically hindered phthalocyanines and their applications to dye-sensitized solar cells [J].

Eu, Seunghun ;

Katoh, Takashi ;

Umeyama, Tomokazu ;

Matano, Yoshihiro ;

Imahori, Hiroshi .

DALTON TRANSACTIONS, 2008, (40) :5476-5483

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