The hydrogen bond

被引：319

作者：

Buckingham, A. D. ^{[1
]}

Del Bene, J. E. ^{[2
]}

McDowell, S. A. C. ^{[1
,3
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

[3] Univ W Indies, Dept Biol & Chem Sci, Bridgetown, Barbados

来源：

CHEMICAL PHYSICS LETTERS | 2008年 / 463卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2008.06.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The concept of the hydrogen bond is a century old but remains youthful because of its vital role in so many branches of science and because of continued advances in experiment, theory and simulation. We discuss the structural and energetic characteristics of normal hydrogen bonds X-H...Y as well as some exceptions to the normal, including proton-shared and ion-pair bonds. We consider the harmonic and anharmonic vibration of X-H in a variety of complexes, and demonstrate that there is no fundamental difference between blue-shifting and red-shifting bonds. We discuss water clusters and liquid water and indicate possible directions of future progress. (c) 2008 Elsevier B.V. All rights reserved

引用

页码：1 / 10

页数：10

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