Some major aspects of the chemical behavior of rare earth oxides: An overview

被引：42

作者：

Bernal, S ^{[1
]}

Blanco, G ^{[1
]}

Calvino, JJ ^{[1
]}

Omil, JAN ^{[1
]}

Pintado, JM ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Ciencia Mat Ingn Met & Quim Inorgan, E-11510 Puerto Real, Cadiz, Spain

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2006年 / 408卷

关键词：

rare earths oxides; sesquioxides; higher oxides; acid-base behavior; redox properties; metal-rare earth oxide interaction phenomena;

D O I：

10.1016/j.jallcom.2004.12.090

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chemical behavior of sesquioxides and higher rare earth oxides is briefly reviewed. In the first case processes implying no change in the lanthanoid oxidation state are considered, whereas in the second one the analysis is focused on their redox behavior. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：496 / 502

页数：7

共 64 条

[1] The binary rare earth oxides [J].

Adachi, G ;

Imanaka, N .

CHEMICAL REVIEWS, 1998, 98 (04) :1479-1514

[2]

Adachi G, 2004, BINARY RARE EARTH OXIDES, P1

[3] Ionic conducting lanthanide oxides [J].

Adachi, GY ;

Imanaka, N ;

Tamura, S .

CHEMICAL REVIEWS, 2002, 102 (06) :2405-2429

[4] THE KINETICS OF LN2O3 HYDRATION UNDER MILD CONDITIONS [J].

ALVERO, R ;

BERNAL, A ;

CARRIZOSA, I ;

ODRIOZOLA, JA ;

TRILLO, JM .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1987, 32 (02) :637-643

[5] Crystal field strength in C-type cubic rare earth oxides [J].

Antic-Fidancev, E ;

Hölsä, J ;

Lastusaari, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 341 (1-2) :82-86

[6] Reversible changes in the redox behaviour of a Ce0.68Zr0.32O2 mixed oxide:: effect of alternating the re-oxidation temperature after reduction at 1223 K [J].

Baker, RT ;

Bernal, S ;

Blanco, G ;

Cordón, AM ;

Pintado, JM ;

Rodríguez-Izquierdo, JM ;

Fally, F ;

Perrichon, V .

CHEMICAL COMMUNICATIONS, 1999, (02) :149-150

[7] STRUCTURAL TRENDS IN LANTHANIDE TRIHYDROXIDES [J].

BEALL, GW ;

MILLIGAN, WO ;

WOLCOTT, HA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (01) :65-70

[8] YTTRIUM CARBONATE HYDROXIDE [J].

BEALL, GW ;

MILLIGAN, WO ;

MROCZKOWSKI, S .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (NOV15) :3143-3144

[9] STUDY OF THE REDUCTION REOXIDATION CYCLE IN A LA/CE/TB MIXED-OXIDE [J].

BERNAL, S ;

BLANCO, G ;

BOTANA, FJ ;

GATICA, JM ;

OMIL, JAP ;

PINTADO, JM ;

RODRIGUEZIZQUIERDO, JM ;

MAESTRO, P ;

BRACONNIER, JJ .

JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 207 :196-200

[10] BEHAVIOR OF RARE-EARTH SESQUIOXIDES EXPOSED TO ATMOSPHERIC CARBON-DIOXIDE AND WATER [J].

BERNAL, S ;

BOTANA, FJ ;

GARCIA, R ;

RODRIGUEZIZQUIERDO, JM .

REACTIVITY OF SOLIDS, 1987, 4 (1-2) :23-40

← 1 2 3 4 5 6 7 →