Photoelectrochemical application of nanotubular titania photoanode

被引：106

作者：

Xie, YB ^{[1
]}

机构：

[1] SE Univ, State Key Lab Bioelect, Nanjing 210096, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2006年 / 51卷 / 17期

关键词：

anodization; photoanode; photoelectrochemistry; photoelectrocatalysis; titania nanotubes;

D O I：

10.1016/j.electacta.2005.10.003

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Titania/titanium (TiO2/Ti) electrodes with tailored surface structure have been fabricated by galvanostatic-potentiostatic anodization process. Highly ordered titania nanotubes array can be prepared by electrolyzing titanium foil at 20 V for 40 min in HF-H3PO4 electrolyte. Comparatively, micro-structured and crystallized TiO2 multiporous film can be prepared at 20-40 V for 6 h in H2SO4-H3PO4-H2O2-HF electrolyte. The morphological characteristics and crystal behaviors of both nanotubular and micro-structured TiO2 films are investigated by field emission scanning electron microscopy and X-ray diffraction measurement. Photoelectrochemical properties of TiO2/Ti film electrodes are examined by anodic photocurrent response and cyclic voltammetry measurement. Photocatalytic and photoelectrocatalytic application are investigated by using either nanotubular TiO2/Ti thin-film or micro-structured TiO2/Ti thick-film electrodes as photoanodes for recalcitrant organic pollutant degradation. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3399 / 3406

页数：8

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