Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols

被引：25

作者：

Hodgson, DM ^{[1
]}

Gibbs, AR ^{[1
]}

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 02期

关键词：

D O I：

10.1016/0957-4166(96)00019-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric synthesis of 4-substituted cis-4-(hydroxymethyl)cyclopent-2-en-1-ols 3 (R = alkyl, benzyloxymethyl) via highly enantioselective rearrangement of 3-substituted cis-6-oxabicyclo[3.1.0]hexane-3-methanols 1 (R = alkyl, benzyloxymethyl) is described.

引用

页码：407 / 408

页数：2

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