Gram-scale synthesis of ultrasmall SnO2 nanocrystals with an excellent electrochemical performance

被引:47
作者
Chen, Yuejiao [1 ]
Ma, Jianmin [1 ]
Li, Qiuhong [1 ]
Wang, Taihong [1 ]
机构
[1] Hunan Univ, Key Lab Micronano Optoelect Devices, Minist Educ, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
N-METHYLIMIDAZOLE; HOLLOW NANOSPHERES; GROWTH-KINETICS; QUANTUM DOTS; LITHIUM; NANOMATERIALS; NUCLEATION; ELECTRODES; NANOSHEETS; ANODES;
D O I
10.1039/c3nr00356f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The gram-scale synthesis of ultrasmall SnO2 nanocrystals has been successfully realized via a solvothermal process, during which the solvent used plays an important role in inhibiting the growth and aggregation of the nanocrystals. When investigating their electrochemical behaviour, the nanocrystal electrode shows an excellent performance in capacity retention and a better rate capacity.
引用
收藏
页码:3262 / 3265
页数:4
相关论文
共 44 条
[1]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[2]   Nucleation and growth kinetics of CdSe nanocrystals in octadecene [J].
Bullen, CR ;
Mulvaney, P .
NANO LETTERS, 2004, 4 (12) :2303-2307
[3]   SnO2 hollow structures and TiO2 nanosheets for lithium-ion batteries [J].
Chen, Jun Song ;
Archer, Lynden A. ;
Lou, Xiong Wen .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) :9912-9924
[4]   Mesoporous SnO2@carbon core-shell nanostructures with superior electrochemical performance for lithium ion batteries [J].
Chen, L. B. ;
Yin, X. M. ;
Mei, L. ;
Li, C. C. ;
Lei, D. N. ;
Zhang, M. ;
Li, Q. H. ;
Xu, Z. ;
Xu, C. M. ;
Wang, T. H. .
NANOTECHNOLOGY, 2012, 23 (03)
[5]   Mesoporous SnO2 nanospheres formed via a water-evaporating process with superior electrochemical properties [J].
Chen, Yuejiao ;
Ma, Jianmin ;
Yu, Ling ;
Li, Qiuhong ;
Wang, Taihong .
CRYSTENGCOMM, 2012, 14 (19) :6170-6172
[6]   Functional Materials for Rechargeable Batteries [J].
Cheng, Fangyi ;
Liang, Jing ;
Tao, Zhanliang ;
Chen, Jun .
ADVANCED MATERIALS, 2011, 23 (15) :1695-1715
[7]   Silicon Nanowire Fabric as a Lithium Ion Battery Electrode Material [J].
Chockla, Aaron M. ;
Harris, Justin T. ;
Akhavan, Vahid A. ;
Bogart, Timothy D. ;
Holmberg, Vincent C. ;
Steinhagen, Chet ;
Mullins, C. Buddie ;
Stevenson, Keith J. ;
Korgel, Brian A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (51) :20914-20921
[8]   Synthesis of n-type CuInS2 Particles Using N-methylimidazole, Characterization and Growth Mechanism [J].
Courtel, Fabrice M. ;
Hammami, Amer ;
Imbeault, Regis ;
Hersant, Gregory ;
Paynter, Royston W. ;
Marsan, Benoit ;
Morin, Mario .
CHEMISTRY OF MATERIALS, 2010, 22 (12) :3752-3761
[9]   Lewis base catalyzed addition of trimethylsilyl cyanide to aldehydes [J].
Denmark, SE ;
Chung, WJ .
JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (10) :4002-4005
[10]   DIRECT APPROACHES TO ZINC POLYCHALCOGENIDE CHEMISTRY - ZNS6(N-MEIM)2 AND ZNSE4(N-MEIM)2 [J].
DEV, S ;
RAMLI, E ;
RAUCHFUSS, TB ;
STERN, CL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6385-6386