Visible-Near Infrared Absorbing Dithienylcyclopentadienone-Thiophene Copolymers for Organic Thin-Film Transistors

被引:57
作者
Yang, Changduk [1 ]
Cho, Shinuk [2 ]
Chiechi, Ryan C.
Walker, Wesley [3 ]
Coates, Nelson E. [2 ]
Moses, Daniel [2 ]
Heeger, Alan J. [2 ]
Wudl, Fred [1 ,2 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
关键词
D O I
10.1021/ja806784e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Structural design, synthesis, and characterization of a series of organic semiconductors consisting exclusively of dithienylcyclopentadienone subunits within a polythiophene backbone are described as the first example for organic electronic devices. The donor (thiophene)-alt-acceptor (cyclopentadienone) copolymers exhibit a substantial p-carrier mobility in OFET but an unexpected noncorrelation between absorption and photoconductivity.
引用
收藏
页码:16524 / +
页数:4
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