A first transition series pseudotetrahedral oxynitride anion:: Synthesis and characterization of Ba2VO3N

被引：19

作者：

Clarke, SJ

Chalker, PR

Holman, J

Michie, CW

Puyet, M

Rosseinsky, MJ

机构：

[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Univ Liverpool, Dept Engn, Liverpool L69 7ZD, Merseyside, England

[3] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 13期

关键词：

D O I：

10.1021/ja0122896

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ammonolysis of reactive oxide precursors affords the vanadium(V) phase Ba2VO3N that is shown by X-ray and neutron powder diffraction and Raman spectroscopy to contain pseudotetrahedral VO3N4- anions. This is the first example of such species for the first transition series metals.

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页码：3337 / 3342

页数：6

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