Direct Observation of Efficient Triplet-Triplet Energy Transfer in Phosphorescent Organic Light-Emitting Diode

被引:8
作者
Fukagawa, Hirohiko [1 ]
Shimizu, Takahisa [1 ]
Osada, Yoshichika [2 ]
Kamada, Taisuke [2 ]
Kiribayashi, Yukihiro [2 ]
Yamamoto, Toshihiro [1 ]
Shimidzu, Naoki [1 ]
机构
[1] Japan Broadcasting Corp NHK, Sci & Technol Res Labs, Setagaya Ku, Tokyo 1578510, Japan
[2] Tokyo Univ Sci, Shinjuku Ku, Tokyo 1628610, Japan
关键词
HIGHLY EFFICIENT; ELECTROLUMINESCENT DEVICES; COMPLEXES;
D O I
10.7567/APEX.6.052104
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report on the energy transfer mechanism between the host and the iridium dopant in phosphorescent organic light-emitting diodes (PHOLEDs). The excited-state energies of the host and the dopant are carefully defined to discuss the energy transfer. The PHOLED using bis(benzo[h]quinolin-10-olato-kN,kO)beryllium(II) (Bebq(2)) as the host and bis(4-pentafluorophenyl-2-phenylpyridine)(acetylacetonate)iridium(III) (m-PF-py) as the dopant shows a maximum external quantum efficiency (eta(ext)) of about 15%, whereas the photoluminescence quantum yield of the emitting layer film is only 19%. The high eta(ext) of the PHOLED implies efficient triplet-triplet energy transfer from Bebq(2) to m-PF-py. (c) 2013 The Japan Society of Applied Physics
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页数:4
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