Preparation of porphyrin-stoppered rotaxane aiming at immobilization on substrate

被引:29
作者
Asakawa, M
Ikeda, T
Yui, N
Shimizu, T
机构
[1] Natl Inst Adv Ind Sci & Technol, Nanoarchitecton Res Ctr, Tsukuba, Ibaraki 3058565, Japan
[2] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuhi, Ishikawa 9231292, Japan
关键词
D O I
10.1246/cl.2002.174
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The porphyrin-stoppered rotaxane was prepared from dibenzo-24-crown-8 (DB24C8) and the secondary ammonium ion derivative end-capped by the axial coordination of rhodium(III) tetra- (3,5-di-tert-butylphenyl) porphyrin [TBPP Rh(III) Cl]. This rotaxane molecule was designed aiming at the immobilization on a substrate and the analysis of the physicochemical properties as a single molecule.
引用
收藏
页码:174 / 175
页数:2
相关论文
共 15 条
  • [1] Asakawa M, 2000, ADV MATER, V12, P1099, DOI 10.1002/1521-4095(200008)12:15<1099::AID-ADMA1099>3.0.CO
  • [2] 2-2
  • [3] Ashton PR, 1996, CHEM-EUR J, V2, P729
  • [4] A molecular meccano kit
    Cantrill, SJ
    Pease, AR
    Stoddart, JF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21): : 3715 - 3734
  • [5] Axially coordinated porphyrins as new rotaxane stoppers
    Chichak, K
    Walsh, MC
    Branda, NR
    [J]. CHEMICAL COMMUNICATIONS, 2000, (10) : 847 - 848
  • [6] A [2]catenane-based solid state electronically reconfigurable switch
    Collier, CP
    Mattersteig, G
    Wong, EW
    Luo, Y
    Beverly, K
    Sampaio, J
    Raymo, FM
    Stoddart, JF
    Heath, JR
    [J]. SCIENCE, 2000, 289 (5482) : 1172 - 1175
  • [7] Fabrication of molecular alignment at the specific sites on Cu(111) surfaces using self-assembly phenomena
    Furukawa, M
    Tanaka, H
    Sugiura, K
    Sakata, Y
    Kawai, T
    [J]. SURFACE SCIENCE, 2000, 445 (01) : L58 - L63
  • [8] Nanoscale science of single molecules using local probes
    Gimzewski, JK
    Joachim, C
    [J]. SCIENCE, 1999, 283 (5408) : 1683 - 1688
  • [9] Thermodynamically self-assembling porphyrin-stoppered rotaxanes
    Gunter, MJ
    Bampos, N
    Johnstone, KD
    Sanders, JKM
    [J]. NEW JOURNAL OF CHEMISTRY, 2001, 25 (01) : 166 - 173
  • [10] High yielding and practical synthesis of rotaxanes by acylative end-capping catalyzed by tributylphosphine
    Kawasaki, H
    Kihara, N
    Takata, T
    [J]. CHEMISTRY LETTERS, 1999, (10) : 1015 - 1016