A copper(II)-lanthanoid(III)-glycine complex with high-nuclearity, [{La6Cu26gly18(μ3-OH)30(H2O)24 (ClO4)}(ClO4)21•26H2O]n

被引：32

作者：

Hu, SM ^{[1
]}

Dai, JC ^{[1
]}

Wu, XT ^{[1
]}

Wu, LM ^{[1
]}

Cui, CP ^{[1
]}

Fu, ZY ^{[1
]}

Hong, MC ^{[1
]}

Liang, YC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2002年 / 13卷 / 01期

基金：

美国国家科学基金会; 中国科学院基金;

关键词：

copper(II); lanthanide(III); amino acids; high nuclearity; 1-D chain;

D O I：

10.1023/A:1015182827959

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1-D complex with high-nuclearity [{La(6)Cu(26)gly(18)(mu(3)-OH)(30)(H2O)(24)(ClO4)} (ClO4)(21) .26H(2)O](n) was synthesized and characterized by X-ray diffraction analysis. The inner core of the basic unit is an octahedron with La3+ ions at its vertexes and Cu2+ ions at the meddles of the twelve edges. Two additional Cu2+ ions are connected to each La3+ vertex to form a [La6Cu24] unit, and adjacent units are interconnected by a pair [Cu(gly)(2)] bridges to give a polymeric chain structure.

引用

收藏

页码：33 / 41

页数：9

相关论文

共 24 条

[1] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [LN2CU4] HEXANUCLEAR CLUSTERS (WHERE LN = TRIVALENT LANTHANIDE) - MECHANISM OF THE GD(III)-CU(II) MAGNETIC INTERACTION [J].

ANDRUH, M ;

RAMADE, I ;

CODJOVI, E ;

GUILLOU, O ;

KAHN, O ;

TROMBE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :1822-1829

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS [J].

BENCINI, A ;

BENELLI, C ;

CANESCHI, A ;

CARLIN, RL ;

DEI, A ;

GATTESCHI, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8128-8136

[3] CRYSTAL AND MOLECULAR-STRUCTURE AND MAGNETIC-PROPERTIES OF A TRINUCLEAR COMPLEX CONTAINING EXCHANGE-COUPLED GDCU2 SPECIES [J].

BENCINI, A ;

BENELLI, C ;

CANESCHI, A ;

DEI, A ;

GATTESCHI, D .

INORGANIC CHEMISTRY, 1986, 25 (04) :572-575

[4] SYNTHESIS, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES OF TETRANUCLEAR COMPLEXES CONTAINING EXCHANGE-COUPLED GD2CU2, DY2CU2 SPECIES [J].

BENELLI, C ;

CANESCHI, A ;

GATTESCHI, D ;

GUILLOU, O ;

PARDI, L .

INORGANIC CHEMISTRY, 1990, 29 (09) :1750-1755

[5]

Blake AJ, 1997, J CHEM SOC DALTON, P485

[6] SYNTHESIS, CRYSTAL-STRUCTURES AND THERMAL-DECOMPOSITION STUDIES OF A SERIES OF COPPER-LANTHANOID COMPLEXES OF 6-METHYL-2-PYRIDONE [J].

BLAKE, AJ ;

CHEREPANOV, VA ;

DUNLOP, AA ;

GRANT, CM ;

MILNE, PEY ;

RAWSON, JM ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (18) :2719-2727

[7] POLYNUCLEAR CU(12)(II)M(6)(III) (M=Y, ND, OR GD) COMPLEXES ENCAPSULATING A CLO4- ANION - [CU(12)M(6)(OH)(24)(H2O)(18)(PYB)(12)(CLO4)](CLO4)(17)CENTER-DOT-NH(2)O (PYB=PYRIDINE BETAINE) [J].

CHEN, XM ;

AUBIN, SMJ ;

WU, YL ;

YANG, YS ;

MAK, TCW ;

HENDRICKSON, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (37) :9600-9601

[8] Synthesis, structures, and magnetic properties of carboxylate-bridged tetranuclear copper(II)-lanthanoid(III) complexes [Cu2Ln2(betaine)10(H2O)8](ClO4)10•2H2O and [Cu2Ln2(betaine)12(ClO4)2](ClO4)8 [J].

Chen, XM ;

Wu, YL ;

Yang, YY ;

Aubin, SMJ ;

Hendrickson, DN .

INORGANIC CHEMISTRY, 1998, 37 (24) :6186-6191

[9] Preparation, structure and preliminary magnetic studies of tri- and tetra-nuclear cobalt-lanthanide carboxylate complexes [J].

Cui, Y ;

Chen, JT ;

Long, DL ;

Zheng, FK ;

Cheng, WD ;

Huang, JS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (18) :2955-2956

[10]

DAO CN, 1988, J LESS-COMMON MET, V136, P339