Preparation, characterization, and mechanical properties of poly(ε-caprolactone)/polylactic acid blend composites

被引:26
作者
Akos, Noel Ibrahim [1 ]
Wahit, Mat Uzir [1 ]
Mohamed, Rahmah
Yussuf, Abdirahman Ali [2 ]
机构
[1] Univ Teknol Malaysia, Fac Chem Engn, Dept Polymer Engn, Skudai Johor Bahru 81310, Malaysia
[2] Kuwait Inst Sci Res, Petr Res & Studies Ctr, Safat 13109, Kuwait
关键词
FIBER; BIODEGRADABILITY;
D O I
10.1002/pc.22488
中图分类号
TB33 [复合材料];
学科分类号
080505 [复合材料];
摘要
Mechanical properties of poly(epsilon-caprolactone) (PCL) and polylactic acid (PLA) blend reinforced with Dura and Tenera palm press fibers were studied. Dicumyl peroxide (DCP) was used as compatibilizer in the blend composites. Fourier transforms infrared spectrophotometer (FTIR) and field emission scanning electron microscope (FESEM) was used to study the effect of treatment on the fibers and fiber/matrix adhesion respectively. The uncompatibilized blend composites exhibited higher Young's modulus than the compatibilized blend composites. Impact strength of compatibilized blend composites of Tenera fibers (FM) increased by 161% at 10 wt% fiber load more than the uncompatibilized blend composites at same fiber load. The Dura fibers (FN) enhanced impact strength by 133% at 10 wt% fiber load. Tensile strength increased by 40% for compatibilized FM blend composites. In conclusion, it was observed that DCP incorporation resulted in good interfacial adhesion as revealed by the FESEM micrographs and evidenced in the improved mechanical properties. POLYM. COMPOS., 2013. (c) 2013 Society of Plastics Engineers
引用
收藏
页码:763 / 768
页数:6
相关论文
共 33 条
[1]
Thermal properties of high density polyethylene composites with natural fibres: Coupling agent effect [J].
Araujo, J. R. ;
Waldman, W. R. ;
De Paoli, M. A. .
POLYMER DEGRADATION AND STABILITY, 2008, 93 (10) :1770-1775
[2]
Mechanical properties of short flax fibre bundle/poly(ε-caprolactone) composites:: Influence of matrix modification and fibre content [J].
Arbelaiz, A. ;
Fernandez, B. ;
Valea, A. ;
Mondragon, I. .
CARBOHYDRATE POLYMERS, 2006, 64 (02) :224-232
[3]
Morphological, mechanical properties and biodegradability of biocomposite thermoplastic starch and polycaprolactone reinforced with sisal fibers [J].
Campos, A. ;
Marconcini, J. M. ;
Imam, S. H. ;
Klamczynski, A. ;
Ortis, W. J. ;
Wood, D. H. ;
Williams, T. G. ;
Martins-Franchetti, S. M. ;
Mattoso, L. H. C. .
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES, 2012, 31 (08) :573-581
[4]
A REVIEW OF THE BIODEGRADABILITY AND UTILITY OF POLY(CAPROLACTONE) [J].
GOLDBERG, D .
JOURNAL OF ENVIRONMENTAL POLYMER DEGRADATION, 1995, 3 (02) :61-67
[5]
Effect of Grafting on Properties of Oil Palm Empty Fruit Bunch Fiber Reinforced Polycaprolactone Biocomposites [J].
Hamid, Mohammad Zhariff Abdul ;
Ibrahim, Nor Azowa ;
Yunus, Wan Md Zin Wan ;
Zaman, Khairul ;
Dahlan, Mohd .
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES, 2010, 29 (18) :2723-2731
[6]
Effect of peroxide crosslinking on thermal and mechanical properties of poly(ε-caprolactone) [J].
Han, Changyu ;
Ran, Xianghai ;
Su, Xuan ;
Zhang, Kunyu ;
Liu, Nanan ;
Dong, Lisong .
POLYMER INTERNATIONAL, 2007, 56 (05) :593-600
[7]
Han S. O., 2012, INT J POLYM SCI, V2012, P8
[8]
Recent developments in chemical modification and characterization of natural fiber-reinforced composites [J].
John, Maya Jacob ;
Anandjiwala, Rajesh D. .
POLYMER COMPOSITES, 2008, 29 (02) :187-207
[9]
Are natural fiber composites environmentally superior to glass fiber reinforced composites? [J].
Joshi, SV ;
Drzal, LT ;
Mohanty, AK ;
Arora, S .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2004, 35 (03) :371-376
[10]
Biodegradation of flax fiber reinforced poly lactic acid [J].
Kumar, R. ;
Yakubu, M. K. ;
Anandjiwala, R. D. .
EXPRESS POLYMER LETTERS, 2010, 4 (07) :423-430