Dendrimers containing zwitterionic [phosphonium anionic zirconocene(IV)] complexes

被引：51

作者：

Cadierno, V ^{[1
]}

Igau, A ^{[1
]}

Donnadieu, B ^{[1
]}

Caminade, AM ^{[1
]}

Majoral, JP ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 09期

关键词：

D O I：

10.1021/om980880e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Formal [3+2] cycloaddition reactions between various aldehydes and 2-phosphino-1-zirconaindene (I) lead to stable anionic zwitterionic zirconocene complexes. Extension of this method to the reaction of internal or terminated aldehyde containing dendrimers with I allows the preparation of the first dendrimers and multidendritic macromolecules containing zwitterionic [phosphonium anionic zirconocene(IV)] complexes.

引用

收藏

页码：1580 / 1582

页数：3

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