Synthesis of a metallamacrocyclic Re(CO)3 complex using a tridentate bridging ligand

被引：44

作者：

Brasey, T ^{[1
]}

Buryak, A ^{[1
]}

Scopelliti, R ^{[1
]}

Severin, K ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 05期

关键词：

host-guest chemistry; metallamacrocycles; rhenium; silver;

D O I：

10.1002/ejic.200300880

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [ReBr3(CO)(3)][NEt4](2) with 3-hydroxy-1,2,3-benzotriazine-4 (3 H) -one in the presence of base gave the ionic rhenium complex [ReBr(C7H4N3O2)(CO)(3)][NEt4] (2) which was crystallographically characterized. A neutral metallamacrocycle 3 was obtained upon abstraction of [NEt4]Br from complex 2. This complex cocrystallizes with an unusual C-3-symmetric [Ag(eta(1)-benzene)(3)(OH2)][BF4] complex as evidenced by single-crystal X-ray diffraction. (C) Wiley-VCH Verlag GmbH Co.

引用

页码：964 / 967

页数：4

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