Preparation and electrochemical lithium storage of flower-like spinel Li4Ti5O12 consisting of nanosheets

被引:210
作者
Tang, Y. F. [1 ]
Yang, L. [1 ]
Qiu, Z. [1 ]
Huang, J. S. [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
基金
国家高技术研究发展计划(863计划);
关键词
Spinel Li4Ti5O12; Nanosheets; Flower; Lithium ion battery; Anode material;
D O I
10.1016/j.elecom.2008.07.049
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this paper, flower-like spinel Li4Ti5O12 consisting of nanosheets was synthesized by a hydrothermal process in glycol solution and following calcination. The as-prepared product was characterized by scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction and cyclic voltammetry. The capacity of the sample used as anode material for lithium ion battery was measured. This structured Li4Ti5O12 exhibited a high reversible capacity and an excellent rate capability of 165.8 m Ahg(-1) at 8 C, indicating potential application for lithium ion batteries with high rate performance and high capacity. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1513 / 1516
页数:4
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