A TTF-TCNQ electrode as a voltammetric analogue of an ion-selective electrode

被引：29

作者：

Cano, Manuel ^{[1
]}

Palenzuela, Beatriz ^{[1
]}

Rodriguez-Amaro, Rafael ^{[1
]}

机构：

[1] Univ Cordoba, Dept Quim Fis & Termodinam Aplicada, E-14071 Cordoba, Spain

来源：

ELECTROANALYSIS | 2006年 / 18卷 / 11期

关键词：

ion sensor; voltammetric detection; TTF-TCNQ; composite electrode; ion selectivity;

D O I：

10.1002/elan.200603500

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A TTF-TCNQ/PVC composite electrode is proposed as a voltammetric cation and anion sensor. The electrode relies on the principle that, during redox processes involving the TCNQ(0/-) couple for cations and the TTF+/0 couple for anions, electrolyte ions are included into lattice sites in the charge neutralization process. This voltammetric ion-sensor provides results that are similar to those of sensors based on two electrodes (viz. one modified with TCNQ for cations and another modified with TTF for anions) but with some practical advantages over them.

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页码：1068 / 1074

页数：7

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