Bistable molecular orientation of a fluorene derivative with an intramolecular charge transfer in a poly(methyl methacrylate) host

被引:3
作者
Apostoluk, A
Nunzi, JM
Perepichka, IF
机构
[1] Univ Angers, UFR Sci, Lab Proprietes Opt Mat & Applicat, UMR 6136,CNRS, F-49045 Angers, France
[2] Univ Technol Troyes, LNIO, CNRS, FRE 2761, F-10010 Troyes, France
[3] Natl Acad Sci Ukraine, LM Litvinenko Inst Phys Prgan & Coal Chem, UA-83114 Donetsk, Ukraine
关键词
D O I
10.1016/j.cplett.2006.02.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The orientation of bistable molecules incorporated in a polymer host is addressed and studied by means of all-optical poling. Molecular reorientation between two stable molecular forms is assigned as the origin of the optically induced second-order nonlinear optical susceptibility. We found a new non-photochromic photo-induced reaction scheme by which efficient all-optical poling is achieved. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:478 / 482
页数:5
相关论文
共 18 条
[1]   Carrier-envelope phase-controlled quantum interference in optical poling [J].
Adachi, S ;
Kobayashi, T .
PHYSICAL REVIEW LETTERS, 2005, 94 (15)
[2]  
[Anonymous], 1987, QUANT ELE
[3]   Quasi-phase-matched gratings printed by all-optical poling in polymer films [J].
Apostoluk, A ;
Chapron, D ;
Gadret, G ;
Sahraoui, B ;
Nunzi, JM ;
Fiorini-Debuisschert, C ;
Raimond, P .
OPTICS LETTERS, 2002, 27 (22) :2028-2030
[4]   Control of the polarization dependence of optically poled nonlinear polymer films [J].
Brasselet, S ;
Zyss, J .
OPTICS LETTERS, 1997, 22 (19) :1464-1466
[5]   Organic donor-acceptor system exhibiting electrical bistability for use in memory devices [J].
Chu, CW ;
Ouyang, J ;
Tseng, HH ;
Yang, Y .
ADVANCED MATERIALS, 2005, 17 (11) :1440-+
[6]   Dynamics of photoinduced second order nonlinearity in dimethylamino-nitrostilbene polymer thin films [J].
Churikov, VM ;
Hsu, CC .
OPTICS COMMUNICATIONS, 2001, 190 (1-6) :367-371
[7]  
DUMONT M, COMMUNICATION
[8]   Quasi-permanent all-optical encoding of noncentrosymmetry in azo-dye polymers [J].
Fiorini, C ;
Charra, F ;
Nunzi, JM ;
Raimond, P .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1997, 14 (08) :1984-2003
[9]  
Frisch M.J., 2004, Gaussian 03
[10]  
Revision C.02