Neutron diffraction study of the oxychloride layered perovskite, (CuCl)LaNb2O7

被引：14

作者：

Caruntu, G

Kodenkandath, TA

Wiley, JB

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Univ New Orleans, Adv Mat Res Inst, New Orleans, LA 70148 USA

来源：

MATERIALS RESEARCH BULLETIN | 2002年 / 37卷 / 03期

基金：

美国国家科学基金会;

关键词：

layered compounds; oxides; neutron scattering;

D O I：

10.1016/S0025-5408(02)00681-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The structure of the oxychloride layered perovskite, (CuCl)LaNb2O7, has been examined by neutron diffraction. Rietveld refinement of room temperature neutron TOF data, while consistent with the previous X-ray study, allows for an improved modeling of the structure. The structure consists of double perovskite layers (LaNb2O7) separated by copper chloride layers. The copper is octahedrally coordinated, bridging between apical oxygens from the perovskite layer and surrounded by four chlorines in the Cu-Cl plane; this gives rise to edge-sharing CuO2Cl4 octahedra. The chlorines within the Cu-Cl plane were found to move off the ideal (0, 0, 1/2) position to a more general position, (x, 0, 1/2). This disorder leads to a combination of four short and two long distances, common to the Jahn-Teller distorted environments for d(9) copper. Structural details are discussed with respect to their influence on the chlorine disorder. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：593 / 598

页数：6

共 13 条

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