Thiomalate complexes of gold(I): preparation, characterization and crystal structures of 1:2 gold to thiomalate complexes

被引：21

作者：

LeBlanc, DJ

Smith, RW

Wang, ZX

HowardLock, HE

Lock, CJL

机构：

[1] Department of Chemistry, McMaster University, Hamilton

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a700827i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of I :2 gold to thiomalate complexes, as ammonium salts, has been described. The crystal structures of both racemic and optically pure samples are described and compared. In each case, the gold atom is linearly co-ordinated to two ligand sulfur atoms Bond lengths and angles are normal.

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页码：3263 / 3267

页数：5

相关论文

共 36 条

[1] MOSSBAUER AND NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPIC STUDIES ON MYOCRISIN, SOLGANOL, AURANOFIN, AND RELATED GOLD(I) THIOLATES [J].

ALSAADY, AKH ;

MOSS, K ;

MCAULIFFE, CA ;

PARISH, RV .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (08) :1609-1616

[2] STRUCTURE OF TETRAPHENYLPHOSPHONIUM BIS(BENZENETHIOLATO)AURATE(I), [P(C6H5)4][AU(C6H5S)2] [J].

BATES, PA ;

WATERS, JM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (JUN) :862-865

[3]

Best S.L., 1996, GOLD BULL, V29, P87, DOI [10.1007/BF02004707, DOI 10.1007/BF03214741]

[4] SYNTHESIS AND CHARACTERIZATION OF GOLD(I) THIOLATES, SELENOLATES, AND TELLUROLATES - X-RAY CRYSTAL-STRUCTURES OF AU4[TEC(SIME3)3]4, AU4[SC(SIME3)3]4, AND PH3PAU[TEC(SIME3)3] [J].

BONASIA, PJ ;

GINDELBERGER, DE ;

ARNOLD, J .

INORGANIC CHEMISTRY, 1993, 32 (23) :5126-5131

[5] (R)-2-BROMO-1,4-BUTANEDIOIC ACID [J].

BRITTEN, JF ;

HOWARDLOCK, HE ;

LEBLANC, D ;

LOCK, CJL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :1222-1224

[6] CRYSTAL AND MOLECULAR-STRUCTURE OF MU-[1,2-BIS(PHENYLTHIO)ETHANE]-BIS-[CHLOROGOLD(I)] [J].

DREW, MGB ;

RIEDL, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (01) :52-55

[7] SYNCHROTRON X-RAY STUDIES OF METAL-BASED DRUGS AND METABOLITES [J].

ELDER, RC ;

EIDSNESS, MK .

CHEMICAL REVIEWS, 1987, 87 (05) :1027-1046

[8] EXAFS AND WAXS STRUCTURE DETERMINATION FOR AN ANTIARTHRITIC DRUG, SODIUM GOLD(I) THIOMALATE [J].

ELDER, RC ;

LUDWIG, K ;

COOPER, JN ;

EIDSNESS, MK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (17) :5024-5025

[9] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[10]

FRICKER SP, 1996, GOLD BULL, V29, P57

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