Dithiolate and diselenolate tin complexes as ligands transfer reagent towards other metals

被引：13

作者：

Cerrada, E ^{[1
]}

Elipe, S ^{[1
]}

Laguna, M ^{[1
]}

Lahoz, F ^{[1
]}

Moreno, A ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

coupling reactions; NMR; mass spectrometry; X-ray diffraction;

D O I：

10.1016/S0379-6779(98)00414-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The reaction of [SnMe2(C3S5)] and [SnMe2(C3S3Se2)] with gold(I) or gold(III) derivatives affords [Au-2(C3S5)(PR3)(2)], [Au-2(C3S3Se2)(PR3)(2)], and [Au(C3S5)(S2CNR2)] respectively. Similar transmetallation reaction between the tin complexes and [Ni(Mes)Br(PPh2Me)(2)] affords {(C3S5)Mes}(2), {(C3S3Se2)Mes}(2), and [Ni(C(3)S(5)Mes)(Mes)(PPh2Me)] in which coupling S-C, Se-C, S-S and Se-Se reactions occurs. Thecstructure of {(C3S5)Mes}(2) has been confirmed by X-Ray studies.

引用

页码：1759 / 1760

页数：2

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