Photo-electrochemical properties of the TiO2-Pt system in aqueous solutions

被引：94

作者：

Bak, T ^{[1
]}

Nowotny, J ^{[1
]}

Rekas, M ^{[1
]}

Sorrell, CC ^{[1
]}

机构：

[1] Univ New S Wales, Sch Mat Sci & Engn, Ctr Mat Res Energy Conservat, Sydney, NSW 2052, Australia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2002年 / 27卷 / 01期

关键词：

D O I：

10.1016/S0360-3199(01)00090-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical characteristics of photo-electrochemical cell (involving photo-anode made of TiO2, and Pt as cathode) were investigated during the light-on and the light-off regimes using the sunlight. Maximum photo-voltage of the open cell involving undoped TiO2 as photo-anode is 0.7 and 1.6 V without and with chemical bias (Delta pH= 14.6), respectively. Application of ceramic Cr-doped TiO2 (involving 1 wt% of Cr2O3) as photo-anode results in a substantial decrease or the cell voltage (to 0.8 V) despite the application of chemical bias. (C) 2001 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.

引用

页码：19 / 26

页数：8

共 30 条

[1] INVESTIGATIONS ON THE MIXED-OXIDE MATERIAL TIO2-IN2O3 IN REGARD TO PHOTOELECTROLYTIC HYDROGEN-PRODUCTION
BABU, KSC
SINGH, D
SRIVASTAVA, ON
[J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1990, 5 (04) : 364 - 368
[2] BARIN I, 1989, THERMOCHEMICAL DA 1, P796
[3] INFLUENCE OF COPPER ADDITION ON OPTICAL-PROPERTIES OF TIO2
BLONDEAU, G
FROELICHER, M
FROMENT, M
GOFF, AHL
ZERBINO, J
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (09) : 1592 - 1596
[4] CORRELATION OF PHOTOCURRENT-VOLTAGE CURVES WITH FLAT-BAND POTENTIAL FOR STABLE PHOTOELECTRODES FOR PHOTOELECTROLYSIS OF WATER
BOLTS, JM
WRIGHTON, MS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (24) : 2641 - 2645
[5] CAMPET G, 1980, J CLAVERIE MAT RES B, V15, P2148
[6] INTENSITY EFFECTS IN ELECTROCHEMICAL PHOTOLYSIS OF WATER AT TIO2 ELECTRODE
CAREY, JH
OLIVER, BG
[J]. NATURE, 1976, 259 (5544) : 554 - 556
[7] CHANDRA S, 1985, PHOTOELECTROCHEMICAL
[8] CHOI W, 1994, J PHYS CHEM-US, V98, P1369
[9] Finklea H. O., 1988, Semiconductor Electrodes, P43
[10] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
FUJISHIMA, A
HONDA, K
[J]. NATURE, 1972, 238 (5358) : 37 - +

← 1 2 3 →