The luminescence of Eu3+ ion in Ca2Al2SiO7

被引：23

作者：

Chuai, XH

Zhang, HJ

Li, FS

Chou, KC

机构：

[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130021, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

[3] Univ Sci & Technol Beijing, Beijing 100082, Peoples R China

来源：

OPTICAL MATERIALS | 2004年 / 25卷 / 03期

基金：

中国国家自然科学基金;

关键词：

optical materials; sol-gel chemistry; luminescence;

D O I：

10.1016/j.optmat.2003.08.008

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ca2Al2SiO7:Eu3+ was prepared by the sol-gel method. Through the emission spectrum of Eu3+ ion, the fluorescence parameters such as Omega(i) (i = 2,4) and radiative transition probabilities of D-5(0)-F-7(j) were calculated. The Pb2+ ion with bigger radius has an effect on the fluorescence spectra of Eu3+ which can be explained by the structure of the matrix. Simultaneously, the energy transfers between mercury-like ions (Pb2+ and Bi3+) and Eu3+ ion were observed. The D-5(4) and D-5(2) energy levels of Eu3+ are the resonance ones for Pb2+ ion. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：301 / 305

页数：5

共 7 条

[1] Long-lasting phosphorescence of Eu2+ in melilite [J].