Electronic states of boron in superconducting MgB2 studied by 11B NMR

被引:20
作者
Gerashenko, AP
Mikhalev, KN
Verkhovskii, SV
D'yachkova, TV
Tyutyunnik, AP
Zubkov, VG
机构
[1] Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620219, Russia
[2] Russian Acad Sci, Inst Solid State Chem, Ekaterinburg, Russia
关键词
Nuclear Magnetic Resonance; Nuclear Magnetic Resonance Spectrum; Electric Field Gradient; Nuclear Magnetic Resonance Data; Knight Shift;
D O I
10.1007/BF03162449
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Nuclear magnetic resonance (NMR) spectra and nuclear spin-lattice relaxation rate T-1(-1) of B-11 have been measured in superconducting polycrystalline MgB2 with T-c(ons) = 39.5 K. It is shown that (T1T)(-1) and the Knight shift K-s are independent of temperature and nearly isotropic above T-c. Both of these quantities are decreased gradually in going to the superconducting state. According to NMR data the density of states near the Fermi level is flat at the scale of about 500 K. Some conclusions on the orbital content of the density of states at the Fermi level were drawn and compared with the results of the band structure calculations.
引用
收藏
页码:157 / 163
页数:7
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