Regioselective acetyl transfer from the aglycon to the sugar in C-glycosylic compounds facilitated by silica gel

被引：16

作者：

Kumazawa, T ^{[1
]}

Akutsu, Y ^{[1
]}

Matsuba, S ^{[1
]}

Sato, S ^{[1
]}

Onodera, J ^{[1
]}

机构：

[1] Yamagata Univ, Fac Engn, Dept Mat Sci & Engn, Yamagata 9928510, Japan

来源：

CARBOHYDRATE RESEARCH | 1999年 / 320卷 / 1-2期

关键词：

C-glycosylic compounds; C-glycoside; 2 '-O-acetyl C-glycoside; regioselective acetyl transfer; silica gel;

D O I：

10.1016/S0008-6215(99)00140-8

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

2'-O-Acetyl C-glycosylic compounds (C-glycosides) were prepared via regioselective acetyl transfer from aglycons to sugar moieties with silica gel in the presence of unprotected primary and secondary hydroxyl groups. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：129 / 137

页数：9

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