High tenacity, high modulus conducting polyaniline composite fibers

被引:22
作者
Hsu, CH [1 ]
Shih, H
Subramoney, S
Epstein, AJ
机构
[1] EI Dupont Nemours & Co, Cent Res & Dev, Wilmington, DE 19880 USA
[2] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA
关键词
lyotropic solution spinning; PPD-T/polyaniline fiber; sulfonation; tenacity; modulus; conductivity;
D O I
10.1016/S0379-6779(98)00340-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High tenacity, high modulus electrically conducting Polyaniline (PAn) composite fibers are prepared from air-gap spinning of lyotropic PAn/poly(p-phenylene terephthalamide), PPD-T, sulfuric acid solutions. For example, tenacity and modulus are in the range of 16 gpd and 270 gpd, respectively for 30 w.% PAn composite fiber. PAn is finely dispersed around PPD-T domains and is oriented parallel to fiber axis, PAn is also sulfonated during the processing and does not require external doping to render the fibers conductive. Electrical conductivity of the fibers continue to turn on even at the concentration as low as below 5 w.% PAn. The fiber containing 30 w.% PAn has conductivity in the range of 0.1 S/cm.
引用
收藏
页码:677 / 680
页数:4
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