The EPR identification of bis(2,4,6-tri-tert-butylphenyl)-1,3-diphosphaallyl radical

被引:6
作者
Alberti, A
Benaglia, M
Guerra, M
Hudson, A
Macciantelli, D
机构
[1] CNR, I Co CEA, Area Ric, I-40129 Bologna, Italy
[2] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1999年 / 08期
关键词
D O I
10.1039/a903893k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The paramagnetic species detected by EPR spectroscopy upon electrochemical reduction of bis(2,4,7-tri-tert-butyl-phenyl)-1,3-diphosphaallene in THF solution has been unambiguously identified as the title radical, the identification being supported by DFT calculations.
引用
收藏
页码:1567 / 1568
页数:2
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