Water soluble dextran-polyacrylamide graft copolymers for capturing metal ions

被引:11
作者
Kutsevol, N
Guenet, JM
Melnyk, N
Sarazin, D
机构
[1] Kyiv Taras Shevchenko Natl Univ, Dept Chem, UA-01003 Kiev, Ukraine
[2] ULP, CNRS, Inst Charles Sadron, F-67083 Strasbourg, France
关键词
graft copolymer; dextran; polyacrylamide; polymer-metal complex;
D O I
10.1002/masy.200650324
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The graft copolymers of Polyacrylamide (PAA) to Dextran (M-w = 20000 and Mw = 70000) have been synthesised by ceric-ion-reduced redox initiation method. Molecular characteristic of graft copolymers were determined from light scattering, SEC, and viscometry data. it was established that the increase of molecular weight of Dextran component up to 3.5 times do not influence essentially organization at molecular level of these copolymers in aqueous solution. Thet D-g-PAA copolymers capable of binding the heavy metal ions.
引用
收藏
页码:201 / 205
页数:5
相关论文
共 8 条
[1]   Syntheses and characterisation of graft copolymers of maize starch and methacrylonitrile [J].
Athawale, VD ;
Lele, V .
CARBOHYDRATE POLYMERS, 2000, 41 (04) :407-416
[2]   Free radical graft copolymerization of methacrylamide onto agar [J].
Athawale, VD ;
Padwaldesai, MP .
EUROPEAN POLYMER JOURNAL, 1999, 35 (07) :1237-1243
[3]   Bisphenol A-based polycarbonates: characterization of commercial samples [J].
Delpech, MC ;
Coutinho, FMB ;
Habibe, MES .
POLYMER TESTING, 2002, 21 (02) :155-161
[4]  
Huglin M., 1972, LIGHT SCATTERING POL
[5]   Radiation modification of water absorption of cassava starch by acrylic acid/acrylamide [J].
Kiatkamjornwong, S ;
Chomsaksakul, W ;
Sonsuk, M .
RADIATION PHYSICS AND CHEMISTRY, 2000, 59 (04) :413-427
[6]   Intramolecular polycomplexes formed by Dextran-grafted polyacrylamide: Effect of the components molecular weight [J].
Kutsevol, N ;
Guenet, JM ;
Melnik, N ;
Rossi, C .
MACROMOLECULAR SYMPOSIA, 2005, 222 :219-224
[7]   Adsorption of Co(II) by a carboxylate-functionalized polyacrylamide grafted lignocellulosics [J].
Shibi, IG ;
Anirudhan, TS .
CHEMOSPHERE, 2005, 58 (08) :1117-1126
[8]   High performance flocculating agent based on partially hydrolysed sodium alginate-g-polyacrylamide [J].
Tripathy, T ;
Singh, RP .
EUROPEAN POLYMER JOURNAL, 2000, 36 (07) :1471-1476