Li-ion conductivity of aluminate and borate complex polymers containing fluoroalkane dicarboxylate

被引：15

作者：

Aoki, T ^{[1
]}

Konno, A ^{[1
]}

Fujinami, T ^{[1
]}

机构：

[1] Shizuoka Univ, Fac Engn, Dept Mat Sci, Hamamatsu, Shizuoka 4328561, Japan

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2004年 / 151卷 / 06期

关键词：

D O I：

10.1149/1.1710894

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Single-ion conducting polymer electrolytes which contain fluoroalkane dicarboxylate substituted aluminate or borate backbone and two methoxy [oligo (ethyleneoxide)] side chains directly bonded to the ate complex centers (aluminum, borate, etc.) were prepared. Borate polymers containing a long ether chain (n=11.8) exhibited high ionic conductivity (10(-5) S cm(-1) at 30degreesC) and high electrochemical stability. The relationship between polymer structure and ionic conductivity is discussed with the partial charge density on oxygen atoms of the ate complex from the calculations in MOPAC. (C) 2004 The Electrochemical Society.

引用

页码：A887 / A890

页数：4

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