N-heterocyclic NCN-pincer palladium complexes:: A source for general, highly efficient catalysts in Heck, Suzuki, and Sonogashira coupling reactions

被引:44
作者
Churruca, F [1 ]
SanMartin, R [1 ]
Tellitu, I [1 ]
Domínguez, E [1 ]
机构
[1] Euskal Herriko Unibersitatea, Zientia & Teknol Fak, Kim Organ Saila 2, Bilbao, Spain
关键词
palladacycles; catalysis; pincer complexes; cross-coupling;
D O I
10.1055/s-2005-922754
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Readily available NCN-pincer palladium complexes comprising two pyrazole units as the source of both N-donor atoms are successfully employed as catalysts in a range of C-C bond-forming reactions. Good to excellent results are obtained in all cases regardless of the electronic nature of the substrates, along with more convenient procedures and comparatively much lower catalysts loadings in Suzuki and Sonogashira couplings. This paper presents the first report of a Sonogashira coupling reaction by means of a NCN catalyst.
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页码:3116 / 3120
页数:5
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