A new apparatus for phase equilibria in reacting mixtures

被引:6
作者
Arlt, W [1 ]
机构
[1] Tech Univ Berlin, Inst Verfahrenstech, Fachgebiet Thermodynam, D-10623 Berlin, Germany
关键词
vapor-liquid equilibria; experimental method; chemical reaction; acetic acid; propionic acid; methanol;
D O I
10.1016/S0378-3812(99)00061-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
The design of reactive distillation columns requires the data for the phase and the reaction equilibrium. The phase equilibrium data for the binary reacting sub-system are difficult to get. A new apparatus has been constructed for reaction rates of half-life of 30 min. Data are presented for methanol with acetic acid and propionic acid at 60 degrees-90 degrees C. These temperatures represent the operation points of technical columns. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:973 / 977
页数:5
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