A Guanidinium Ion-Based Anion- and Solvent Polarity-Controllable Molecular Switch

被引：51

作者：

Lin, Tzu-Chiun ^{[1
]}

Lai, Chien-Chen ^{[2
]}

Chiu, Sheng-Hsien ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan

[2] China Med Univ Hosp, Dept Med Genet, Taichung, Taiwan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 03期

关键词：

ONE-POT SYNTHESIS; TRANSLATIONAL ISOMERISM; RECOGNITION; PSEUDOROTAXANE; RECEPTORS; SHUTTLES; LIGHT; COMPLEXES; STIMULI; MACHINE;

D O I：

10.1021/ol802638k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The macrocycle bis-p-xylyl[26]crown-6 (BPX26C6) is capable of complexing guanidinium ions in a [2]pseudorotaxane-like manner in solution. A corresponding molecular switch can be operated through changes in solvent polarity or the addition and removal of halogen and acetate anions.

引用

页码：613 / 616

页数：4

共 34 条

[31] Photo-driven molecular devices [J].

Saha, Sourav ;

Stoddart, J. Fraser .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (01) :77-92

[32]

SHIMONI L, 1995, PROTEIN SCI, V4, P65

[33] Redox-controllable amphiphilic [2]rotaxanes [J].

Tseng, HR ;

Vignon, SA ;

Celestre, PC ;

Perkins, J ;

Jeppesen, JO ;

Di Fabio, A ;

Ballardini, R ;

Gandolfi, MT ;

Venturi, M ;

Balzani, V ;

Stoddart, JF .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :155-172

[34] Dual-action acid/base- and base/acid-controllable molecular switch [J].

Yen, Ming-Liang ;

Li, Wan-Sheung ;

Lai, Chien-Chen ;

Chao, Ito ;

Chiu, Sheng-Hsien .

ORGANIC LETTERS, 2006, 8 (15) :3223-3226

← 1 2 3 4 →