High symmetry effects on hydrogen bond rearrangement:: The 4.1 THz vibrational band of (D2O)4

被引：18

作者：

Brown, MG ^{[1
]}

Keutsch, FN ^{[1
]}

Braly, LB ^{[1
]}

Saykally, RJ ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 17期

关键词：

D O I：

10.1063/1.480115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vibration-rotation-tunneling (VRT) spectroscopy has been extended to the 4 THz spectral region through the observation of a second intermolecular vibration of (D2O)(4). Analysis of the precisely measured perpendicular transition confirms the previously reported cyclic homodromic structure and reveals a dramatically increased (30x) hydrogen bond rearrangement rate in the excited state. (C) 1999 American Institute of Physics. [S0021-9606(99)00441-9].

引用

页码：7801 / 7806

页数：6

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