Minimizing interfacial losses in inverted organic solar cells comprising Al-doped ZnO

被引:40
作者
Gadisa, Abay [1 ]
Liu, Yingchi [2 ]
Samulski, Edward T. [1 ]
Lopez, Rene [2 ]
机构
[1] Univ N Carolina, Dept Chem, Caudill & Kenan Labs, Chapel Hill, NC 27515 USA
[2] Univ N Carolina, Dept Phys & Astron, Chapel Hill, NC USA
基金
美国国家科学基金会;
关键词
OPEN-CIRCUIT VOLTAGE; CONJUGATED POLYELECTROLYTE; POLYMER; EFFICIENCY; PERFORMANCE; OXIDE;
D O I
10.1063/1.4729861
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrated a 35% enhancement in the efficiency of inverted solar cells as a result of increased open-circuit voltage and fill factor by adsorbing an ultrathin layer of a ruthenium dye N719 on an aluminum-doped zinc oxide (ZnO-Al) electron collecting interfacial layer. The interface modification with N719 changes the charge injection levels as indicated by ultraviolet photoemission spectroscopy. The efficiency of inverted solar cells comprising a bulk heterojunction photo-active film of poly(3-hexylthiophene) and phenyl-C-61-butyric acid methyl ester has increased from similar to 2.80% to 3.80% upon employing the dye modification of the electrode interface. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4729861]
引用
收藏
页数:4
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