Synthesis and single-crystal X-ray characterization of 4,4"-functionalized 4′(4-bromophenyl)-2,2′:6′,2"-terpyridines

被引：75

作者：

Eryazici, I

Moorefield, CN

Durmus, S

Newkome, GR ^{[1
]}

机构：

[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[2] Univ Akron, Dept Chem, Akron, OH 44325 USA

[3] Univ Akron, Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 03期

关键词：

D O I：

10.1021/jo052036l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

To expand the utility of bis(terpyridine) metal connectivity, the selective symmetrical and unsymmetrical 4,4"-functionalization (-CN, -Me, -CO2Me) of 4'-(4-bromophenyl)-2,2':6',2"-terpyridines was achieved using the Krohnke synthesis The final substituted 2,2':6',2"-terpyridines along with their corresponding intermediates, 4a-c, were recrystallized and characterized by H-1 NMR and C-13 NMR as well as X-ray crystallography; COSY correlations were also conducted to permit definitive proton assignment.

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页码：1009 / 1014

页数：6

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