Synthesis, structure and near-infrared (NIR) luminescence of three solvent-induced pseudo-polymorphic complexes from a bimetallic Zn-Nd Schiff-base molecular unit

被引:36
作者
Bi, Wei-Yu [1 ]
Lue, Xing-Qiang [1 ,2 ]
Chai, Wen-Li [1 ]
Jin, Wen-Juan [1 ]
Song, Ji-Rong [1 ]
Wong, Wai-Kwok [2 ]
机构
[1] NW Univ Xian, Coll Chem Engn, Shaanxi Key Lab Physinorgan Chem, Xian 710069, Shaanxi, Peoples R China
[2] Hong Kong Baptist Univ, Dept Chem, Hong Kong, Hong Kong, Peoples R China
关键词
Solvent-induced pseudo-polymorphism; Bimetallic Zn-Nd Schiff-base complex; Intermolecular pi-pi interaction; NIR luminescence;
D O I
10.1016/j.inoche.2008.08.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three solvent-induced pseudo-polymorphic bimetallic Zn-Nd complexes [ZnNdL(OAc)(NO3)(2)(DMF)] solvate (solvate: MeCN (1), THF (2), EtOH (3): H2L = N,N'-bis(3-methoxy-salicylidene)phenylene-1,2-diamine) were obtained, and their solid NIR luminescence related to the packing structure from the intermolecular pi-pi interactions was discussed. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1316 / 1319
页数:4
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