The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents

被引：61

作者：

de Greef, Tom F. A. ^{[1
]}

Nieuwenhuizen, Marko M. L. ^{[1
]}

Stals, Patrick J. M. ^{[1
]}

Fitie, Carel F. C. ^{[1
]}

Palmans, Anja R. A. ^{[1
]}

Sijbesma, Rint P. ^{[1
]}

Meijer, E. W. ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 36期

关键词：

D O I：

10.1039/b806506c

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain.

引用

页码：4306 / 4308

页数：3

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