Highly efficient organic blue electrophosphorescent devices based on 3,6-bis(triphenylsilyl)carbazole as the host material

被引:452
作者
Tsai, Ming-Han
Lin, Hao-Wu
Su, Hai-Ching
Ke, Tung-Huei
Wu, Chung-Chih [1 ]
Fang, Fu-Chuan
Liao, Yuan-Li
Wong, Ken-Tsung
Wu, Chih-I
机构
[1] Natl Taiwan Univ, Dept Elect Engn, Taipei 106, Taiwan
[2] Natl Taiwan Univ, Grad Inst Electroopt Engn, Taipei 106, Taiwan
[3] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[4] Natl Taiwan Univ, Dept Chem, Grad Inst Elect Engn, Taipei 106, Taiwan
关键词
D O I
10.1002/adma.200502283
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Blue electrophosphorescence in organic light-emitting diodes (OLEDs) is enhanced by the use of 3,6-bis(triphenylsilyl)carbazole (see figure). This carbazole derivative with sterically bulky and large-gap triphenylsilyl groups is an electrochemically and morphologically stable efficient host material for blue electrophosphorescence. When utilized in OLEDs, high efficiencies of up to 16 %, 30.6 cd A(-1), and 26.7 Im W-1 are achieved.
引用
收藏
页码:1216 / +
页数:6
相关论文
共 19 条
[1]   Nearly 100% internal phosphorescence efficiency in an organic light-emitting device [J].
Adachi, C ;
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5048-5051
[2]   Endothermic energy transfer: A mechanism for generating very efficient high-energy phosphorescent emission in organic materials [J].
Adachi, C ;
Kwong, RC ;
Djurovich, P ;
Adamovich, V ;
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 2001, 79 (13) :2082-2084
[3]   ANODIC OXIDATION PATHWAYS OF CARBAZOLES .1. CARBAZOLE AND N-SUBSTITUTED DERIVATIVES [J].
AMBROSE, JF ;
NELSON, RF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1968, 115 (11) :1159-&
[4]   ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES OF CATION RADICALS .3. REACTION PATHWAYS OF CARBAZOLIUM RADICAL IONS [J].
AMBROSE, JF ;
CARPENTER, LL ;
NELSON, RF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (07) :876-894
[5]   Quantum-chemical design of host materials for full-color triplet emission [J].
Avilov, I ;
Marsal, P ;
Brédas, JL ;
Beljonne, D .
ADVANCED MATERIALS, 2004, 16 (18) :1624-+
[6]   Highly efficient phosphorescent emission from organic electroluminescent devices [J].
Baldo, MA ;
O'Brien, DF ;
You, Y ;
Shoustikov, A ;
Sibley, S ;
Thompson, ME ;
Forrest, SR .
NATURE, 1998, 395 (6698) :151-154
[7]   Carbazole compounds as host materials for triplet emitters in organic light-emitting diodes:: Tuning the HOMO level without influencing the triplet energy in small molecules [J].
Brunner, K ;
van Dijken, A ;
Börner, H ;
Bastiaansen, JJAM ;
Kiggen, NMM ;
Langeveld, BMW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6035-6042
[8]   Improved synthesis of 2,2'-dibromo-9,9'-spirobifluorene and its 2,2'-bisdonor-7,7'-bisacceptor-substituted fluorescent derivatives [J].
Chiang, CL ;
Shu, CF ;
Chen, CT .
ORGANIC LETTERS, 2005, 7 (17) :3717-3720
[9]   PEDT/PSS for efficient hole-injection in hybrid organic light-emitting diodes [J].
Elschner, A ;
Bruder, F ;
Heuer, HW ;
Jonas, F ;
Karbach, A ;
Kirchmeyer, S ;
Thurm, S .
SYNTHETIC METALS, 2000, 111 :139-143
[10]   Triplet exciton confinement and unconfinement by adjacent hole-transport layers [J].
Goushi, K ;
Kwong, R ;
Brown, JJ ;
Sasabe, H ;
Adachi, C .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (12) :7798-7802