Morphologies of spin-coated films of a library of diblock copoly(2-oxazoline)s and their correlation to the corresponding surface energies

被引：25

作者：

Hoeppener, S

Wiesbrock, F

Hoogenboom, R

Thijs, HML

Schubert, US

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 06期

关键词：

diblock copolymers; film morphology; library; material properties; poly(2-oxazoline); scanning force microscopy; surface energy;

D O I：

10.1002/marc.200500863

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of surface morphologies on the properties of materials is of essential importance and is therefore a widely discussed topic. In the present contribution, the properties of a set of diblock copoly(2-oxazoline)s are analyzed in terms of their individual morphologies, which have been investigated with tapping-mode SFM. This collection of diblock copolymers consists of 12 diblock copolymers and four corresponding homopolymers, representing 1 complete 16-membered library of (co-) poly(2-oxazoline)s, composed of four differently substituted 2-oxazoline monomers. For the investigated set of compounds, a correlation between the morphologies of the spin-coated films and their surface energies could be determined.

引用

收藏

页码：405 / 411

页数：7

相关论文

共 30 条

[1] Polymerization of oxazolines [J].

Aoi, K ;

Okada, M .

PROGRESS IN POLYMER SCIENCE, 1996, 21 (01) :151-208

[2] PREPARATION AND CHARACTERIZATION OF PHENYL AND UNDECYL OXAZOLINE BLOCK COPOLYMERS [J].

CAI, GF ;

LITT, MH .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (11) :3603-3618

[3] A NOVEL NONIONIC HYDROGEL FROM 2-METHYL-2-OXAZOLINE [J].

CHUJO, Y ;

YOSHIFUJI, Y ;

SADA, K ;

SAEGUSA, T .

MACROMOLECULES, 1989, 22 (03) :1074-1077

[4] IRON(II) BIPYRIDYL-BRANCHED POLYOXAZOLINE COMPLEX AS A THERMALLY REVERSIBLE HYDROGEL [J].

CHUJO, Y ;

SADA, K ;

SAEGUSA, T .

MACROMOLECULES, 1993, 26 (24) :6315-6319

[5] A NOVEL NONIONIC HYDROGEL FROM 2-METHYL-2-OXAZOLINE .2. SYNTHESIS OF NONIONIC HYDROGEL, LIPOGEL, AND AMPHIGEL BY COPOLYMERIZATION OF 2-OXAZOLINES AND A BISOXAZOLINE [J].

CHUJO, Y ;

SADA, K ;

MATSUMOTO, K ;

SAEGUSA, T .

MACROMOLECULES, 1990, 23 (05) :1234-1237

[6] Dioxalbicyclooctanyl naphthalenenitriles as nonredox 5-lipoxygenase inhibitors: Structure-activity relationship study directed toward the improvement of metabolic stability [J].

Delorme, D ;

Ducharme, Y ;

Brideau, C ;

Chan, CC ;

Chauret, N ;

Desmarais, S ;

Dube, D ;

Falgueyret, JP ;

Fortin, R ;

Guay, J ;

Hamel, P ;

Jones, TR ;

Lepine, C ;

Li, C ;

McAuliffe, M ;

McFarlane, CS ;

NicollGriffith, DA ;

Riendeau, D ;

Yergey, JA ;

Girard, Y .

JOURNAL OF MEDICINAL CHEMISTRY, 1996, 39 (20) :3951-3970

[7] Reductions of the glass transition temperature in thin polymer films: Probing the length scale of cooperative dynamics [J].

Forrest, JA ;

Mattsson, J .

PHYSICAL REVIEW E, 2000, 61 (01) :R53-R56

[8] Accelerated pressure synthesis and characterization of 2-oxazoline block copolymers [J].

Hoogenboom, R ;

Fijten, MWM ;

Paulus, RM ;

Thijs, HML ;

Hoeppener, S ;

Kickelbick, G ;

Schubert, US .

POLYMER, 2006, 47 (01) :75-84

[9] Microwave-assisted synthesis and properties of a series of poly(2-alkyl-2-oxazoline)s [J].

Hoogenboom, R ;

Fijten, MWM ;

Thijs, HML ;

Van Lankvelt, BM ;

Schubert, US .

DESIGNED MONOMERS AND POLYMERS, 2005, 8 (06) :659-671

[10] Microwave accelerated polymerization of 2-phenyl-2-oxazoline: Microwave or temperature effects? [J].

Hoogenboom, R ;

Leenen, MAM ;

Wiesbrock, F ;

Schubert, WS .

MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (22) :1773-1778