Multiple C-H bond activation.: Threefold-deprotonated 6-phenyl-2,2′-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives

被引：73

作者：

Zucca, A

Doppiu, A

Cinellu, MA

Stoccoro, S

Minghetti, G

Manassero, M

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] Univ Milan, Ctr CNR, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 05期

关键词：

D O I：

10.1021/om010913h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)(2)(DMSO)(2)] (R = Me, Ph) and 6-phenyl-2,2'-bipyridine. The behavior of the substituted 2,2'-bipyridine as a threefold-deprotonated ligand is unprecedented.

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页码：783 / 785

页数：3

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