Aromatic Compounds from Lignin Liquefaction over ZSM-5 Catalysts in Supercritical Ethanol

被引:17
作者
Fan, Di [1 ]
Xie, Xinan [1 ]
Li, Yan [1 ]
Li, Lu [1 ]
Sun, Jiao [1 ]
机构
[1] South China Agr Univ, Coll Food Sci, Wushan St, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Alkali lignin; Aromatic compounds; Liquefaction; Supercritical fluids; Zeolite catalyst; SUBCRITICAL WATER; BIOMASS; DEPOLYMERIZATION; PYROLYSIS; PRODUCTS; HZSM-5; YIELD;
D O I
10.1002/ceat.201700396
中图分类号
TQ [化学工业];
学科分类号
081705 [工业催化];
摘要
A systematic research about the liquefaction of alkali lignin in supercritical ethanol using ZSM-5 zeolite catalysts is reported, which includes the synergistic effect of temperature, catalytic content, and reaction time on product yield and distribution. Fourier transform infrared and gas chromatography-mass spectrometry analysis were carried out to evaluate the compositions of bio-oil and solid residue. Under moderate condition, maximum conversion and yield of bio-oil were satisfactorily high. With the help of ZSM-5 catalyst, lignin could be successfully converted into aromatic compounds.
引用
收藏
页码:509 / 516
页数:8
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