Studies of complex formation between anthraquinones and metal ions by electrospray ionization mass spectrometry

被引：4

作者：

Arakawa, R ^{[1
]}

Sasao, A

Abura, T

Suzuki, T

Fujitake, N

机构：

[1] Kansai Univ, Dept Appl Chem, Osaka 5648680, Japan

[2] Kobe Univ, Dept Biol & Environm Sci, Kobe, Hyogo 6578501, Japan

来源：

EUROPEAN JOURNAL OF MASS SPECTROMETRY | 2001年 / 7卷 / 06期

关键词：

electrospray; ESI-MS; anthraquinones; metal complexation;

D O I：

10.1255/ejms.462

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The metal complexation of the hydroxyanthraquinones, chrysotalunin, chrysophanol and their derivatives, with Al3+, Ni2+ and Zn2+ was studied by electrospray ionization mass spectrometry (ESI-MS). The results showed that chrysophanol and its derivatives form metal complexes with Al3+, Ni2+ and Zn2+ ions, but chrysotalunin does not. Among the metal ions, Al3+ was found to form the complexes most easily.

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收藏

页码：467 / 471

页数：5

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