One-pot electrochemical generation of a porphyrin dimer with a bis(diphenylphosphonium)acetylene bridge

被引：32

作者：

Ruhlmann, L ^{[1
]}

Giraudeau, A ^{[1
]}

机构：

[1] UNIV STRASBOURG 1, LAB ELECTROCHIM & CHIM PHYS CORPS SOLIDE, URA CNRS 405, F-67000 STRASBOURG, FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical oxidation of zinc tetraphenylporphyrin in the presence of bis(diphenyl-phosphino)acetylene leads to the formation of a beta-bridged dimer using 0.5 equiv, of Lewis base per mole of [Zn(tpp)]; a mixture of monomer and dimer is observed when stoichiometric amounts or an excess of diphosphine was used.

引用

页码：2007 / 2008

页数：2

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