Synthesis of organoboron π-conjugated polymers by hydroboration polymerization between heteroaromatic diynes and mesitylborane and their light emitting properties

被引：66

作者：

Matsumi, N ^{[1
]}

Miyata, M ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

MACROMOLECULES | 1999年 / 32卷 / 13期

关键词：

D O I：

10.1021/ma980785h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The hydroboration polymerization of heteroaromatic diynes (2,5-diethynylthiophene, 2,5-diethynylfuran, and 2,5-diethynylpyridine) with mesitylborane was examined. During polymerization, a donor-acceptor was obtained including conjugated polymers without complexation. A significant ground-state charge-transfer interaction was observed. Upon irradiation of UV light, visible green or white emission was observed.

引用

页码：4467 / 4469

页数：3

共 18 条

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