Synthesis and electronic behaviors of TiO2/carbon clusters/Cr2O3 composite materials

被引：34

作者：

Miyazaki, H. ^{[2
]}

Matsui, H. ^{[2
]}

Nagano, T. ^{[2
]}

Karuppuchamy, S. ^{[1
]}

Ito, S. ^{[2
]}

Yoshihara, M. ^{[2
]}

机构：

[1] Kinki Univ, Mol Engn Inst, Fukuoka 8208555, Japan

[2] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Osaka 5778502, Japan

来源：

APPLIED SURFACE SCIENCE | 2008年 / 254卷 / 22期

关键词：

nano-structures; polymers; carbon clusters; titanium dioxide; electron transfer;

D O I：

10.1016/j.apsusc.2008.05.332

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Nano- structured TiO2/carbon clusters/Cr2O3 composite material has been successfully obtained by the microwave treatment of a TiO(acac)/Cr(acac)(3)/epoxy resin complex. The compositions of the composite materials were determined using ICP, elemental analysis and surface characterization by SEM-EDX, TEM and XRD. ESR spectral examinations suggest the possibility of an electron transfer in the process of TiO2 --> carbon clusters --> Cr2O3 with an oxidation site at TiO2 particles and a reduction site at Cr2O3 particles. The preliminary experimental results show that the calcined materials could decompose methylene blue under visible-light irradiation. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：7365 / 7369

页数：5

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