Stille coupling made easier - The synergic effect of copper(I) salts and the fluoride ion

被引：279

作者：

Mee, SPH ^{[1
]}

Lee, V ^{[1
]}

Baldwin, JE ^{[1
]}

机构：

[1] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 09期

关键词：

copper; cross-coupling; fluorides; Stille reaction;

D O I：

10.1002/anie.200352979

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CsF and Cul do the trick: Stille coupling reactions of aryl/vinyl iodides, triflates, and bromides with aryl/vinyl stannanes are greatly enhanced by the inclusion of CsF and Cul in the reaction mixture (see scheme; Conditions A: [Pd(PPh3)4]/CsF/ Cul/DW/45 °C; Conditions B: PdCl 2/ PtBu3/CsF/Cul/DMF/45 °C).

引用

页码：1132 / 1136

页数：5

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